A magnetoresistive element including a silicon and/or a diffusion control layer

ABSTRACT

An MR (Magneto Resistance) effect element includes a free magnetic layer having a small coercive force and therefore reduces the hysteresis of the R-H loop. An MR effect sensor and an MR sensing system using the above MR effect elenient and featuring a desirable noise characteristic are also disclosed.

BACKGROUND OF THE INVENTION

[0001] The present invention relates to a magnetic sensor for reading data signals stored in a magnetic recording medium.

[0002] A magnetic read transducer called an MR (Magneto Resistance) effect sensor or an MR effect head is conventional and capable of reading data out of a magnetic surface with high linear density. as reported in the past. The MR effect sensor or head senses a magnetic field signal in terms of the variation of resistance which is the function of the intensity and direction of a magnetic flux sensed by a reading device. The conventional read transducer is based on an AMR (Anisotropic Magneto Resistance) effect. i.e., the fact that one component of the resistance of a reading device varies in proportion to the square of the cosine of an angle between the direction of magnetfzation and the direction of a sense current flowing through the reading device.

[0003] For details of the AMR effect, reference may be made to D. A. Thompson et al. “Memory, Storage, and Related Applications”, IEEE Trans. on Mag. MAG-11. p. 1039 (1975).

[0004] It is a common practice with a magnetic head utilizing the AMR effect to apply a longitudinal bias magnetic field for reducing Barkhausen noise. To apply the vertical bias magnetic field, use is sometimes made of FeMn. NiMn, nickel oxide or similar antiferromagnetic material. There has recently been reported a more noticeable MR effct, i. e., the fact that the resistance of a laminate magnetic sensor is ascribable to the spin-dependent transfer of conductive electrons occurring between magnetic layers via a nonmagnetic layer and spin-dependent diffusion occurring at an interface between layers due to the above transfer. This kind of MR effect is generally referred to as. e.g., a macro MR effect or a spin valve effect.

[0005] The above MR sensor is formed of a suitable material and has higher sensitivity than a sensor using the AMR effect and therefore noticeably varies in resistance. In this kind of MR effect sensor, two ferromagnetic layers are separated from each other by a nonmagnetic layer. Resistance in the plane between the two ferromagnetic layers varies in proportion to the cosine of an angle between the magnetization directions of the ferromagnetic layers.

[0006] Japanese Patent Laid-Open Publication No. 2-1572, for example, discloses a laminate magnetic structure featuring high MR variation based on the anti parallel alignment of magnetization in a magnetic layer. As for materials usable for the laminate structure, the above document mentions ferromagnetic transition metals and alloys. Further, the document teaches a structure in which an antiferromagnetic layer is added to one of at least two ferromagnetic layers, and indicates that FeMn is feasible for the antiferromagnetic foyer.

[0007] Japanese Patent Laid-Open Publication No. 4-358310 proposes an MR sensor including two thin ferromagnetic layers separated from eachotherbyathinrnonmagneticrmetal layer. When no magnetic field is applied to this MR sensor, the magnetization directions of the two ferromagnetic layers are perpendicular to each other. Resistance between the two non-coupled ferromagnetic layers varies in proportion to the cosine of the angle between the above magnetization directions independently of the direction of current flowing through the sensor.

[0008] Japanese Patent Laid-Open Publication No. 6-203340 discloses an MR sensor also based on the above effect and including two thin ferromagnetic layers separated by a nonmagnetic thin metal layer. When the outside magnetic field is zero, the magnetization of an adjoining antiferromagnetic layer remains perpendicular to the magnetization of the other ferromagnetic layer.

[0009] Japanese Patent Laid-Open Publication No. 7-262529 teaches an MR effect element or spin valve made up of a first magnetic layer, a nonmagnetic layer, a second magnetic layer, and an antiferromagnetic layer. For the first and second magnetic layers, use is made of CoZrNb, CoZrMo, FeSiAl, FeSi or NiFe with or without Cr, Mn, Pt, Ni, Cu, Ag, Al, Ti, Fe, Co or Zn added thereto.

[0010] Japanese Patent Laid-Open Publication No. 7-202292 proposes an MR effect film including a plurality of magnetic thin films laminated on a substrate and separated by a nonmagnetic layer. An antiferrcmsignetic thin layer adjoins one of soft magnetic thin films adjoining each other with the intermediary of a nonmagnetic thin fiIm. Assume that a bias magnetic field applied to the antiferromagnetic thin film is H_(r), and that the coercive force of the other soft magnetic thin film is H_(c2). Then, a relation H_(c2)<H_(r) holds. The antiferromagnetic material is implemented by at least one of NiO, CoO, FeO, Fe₂O₃, MnO and Cr or a mixture thereof.

[0011] Japanese Patent Laid-Open Publication No. 8-127864 teaches an MR effect film similar to the above film except that the antiferromagnetic thin layer is implemented as a superlattice consisting of at least two of NiO, Ni_(x)Co_(i-x)O and CoO.

[0012] Further. Japanese Patent Laid-Open Publication No. 8-2O4253 discloses an MR effect film similar to the above film except that the antiferromagnetic layer is a superlattice consisting of at least two of NiO, Ni_(x)Co_(i-x)O=(x=0.1-0.9), and CoO. In the superIattice, the ratio of Ni to Co in the number of atoms is greater than 1.0 inclusive.

[0013] As for an effect MR element basically consisting of a free magnetic layer. a nonmagnetic layer. a fixed magnetic layer and a fixing magnetic layer, it is preferable that the free magnetic layer has an easy axis of a uniaxial magnetic anisotropy substantially perpendicular to the magnetization direction of the fixed layer.

[0014] The above type of IR effect element should preferably be designed and used such that the magnetization direction of the free magnetic layer and that of the fixed layer are substantially perpendicular to each other in a zero magnetic field. At this instant, if the easy axis direction of the free magnetic layer and the magnetization direction of the fixed layer make an angle c lose to a right angle, then a magnetic field (leakage magnetic field from a record mark on a magnetic recording medium with respect to the operation of a read head) is applied in the hard axis direction of the free magnetic layer. This successfully reduces the coercive force of the free magnetic layer and thereby reduces the hysteresis of the R-H loop when the MR effect element is used as a read sensor. It is therefore possible to reduce the noise of a reproduced signal.

[0015] However, many of the conventional MR elerents use an antiferromagnetic material for the fixing layer. Further, many of antiferromagnetic materials expected to be put to practical use as a fixing layer must be heated at temperatures above 200° C. in a magnetic field parallel to the magnetization direction of the fixed layer, so that a sufficient exchange coupled magnetic field can be applied to the fixed layer.

[0016] In each of the conventional MR effect element of the type described, the anti ferromagnetic layer is formed after the formation of the free magnetic layer, nonmagnetic layer, and fixed magnetic layer. Therefore, the above heat treatment acts not only on the fixed magnetic layer and fixing magnetic layer but also on the free magnetic layer. Consequently, the easy axis of the uniaxial magnetic anisotropy of the free magnetic layer is oriented parallel to the direction of the magnetic field, i.e., the magnetization direction of the fixed magnetic layer. This increases the coercive force of the free magnetic layer and thereby increases noise when the MR effect film is used as a sensor.

[0017] Technologies relating to the present invention are a1so disclosed in, e.g., Japanese Patent Laid-Open Publication No. 9-199326.

SUMMARY OF THE INVENTION

[0018] It is therefore an object of the present invention to provide an MR effect element capable of reducing the coercive force of its free magnetic layer and therefore the hysteresis of the R-H loop, and an MR effect sensor and an MR sensing system using the same and featuring a desirable noise characteristic.

[0019] In accordance with the present invention, in an MR effect element, a laminate film is implemented by a unit consisting of an Si layer, a metal lower layer, a free magnetic layer, a nonmagnetic layer, a fixed layer, and a magnetic fixing layer.

[0020] Also, in accordance with the present invention, in an MR effect element, a laminate film is implemented by a unit consisting of an Si layer, a diffusion control layer, a metal lower layer, a free magnetic layer, a nonmagnetic layer, a fixed layer, and a magnetic fixing layer.

BRIEF DESCRIPTION OF THE DRAWINGS

[0021] The above and other objects, features and advantages of the present invention will becnme more apparent from the following detailed description taken with the accompanying drawings in which:

[0022]FIGS. 1 and 2 each shows a particular typical configuration of an MR sensor;

[0023]FIG. 3 is 8 perspective view showing the general construction of a read/write head;

[0024]FIG. 4 shows the general configuration of a recording/reproducing apparatus;

[0025]FIG. 5 is a table listing the coercive forces end saturation magnetic fields of a free magnetic layer and magnetoresistance (MR) ratios measured at different substrate temperatures;

[0026]FIGS. 6 and 7 are tables each listing the coercive forces and saturation magnetic fields of free magnetic layer included in samples and MR ratios measured after heat treatment;

[0027]FIG. 8 is a table listing the coercive forces and saturation magnetic fields of a free magnetic layer and MR ratias measured at different heat treatment temperatures (heat treatment temperatures A);

[0028]FIG. 9 is a table listiing the coercive forces and saturation magnetic fields of free magnetic layers included in samples and MR ratios measured after heat treatment;

[0029]FIG. 10 is a table listing the coercive forces and saturation magnetic fields of a free magrietic layer and MR ratios measured at different substrate temperatures;

[0030]FIG. 11 is a table listing the coercive forces and saturation magnetic fields of a free magnetic layer and MR ratios measured at different heat treatment temperatures (heat treatment temperatures B);

[0031]FIG. 12 is a table listing the coercive forces and saturation magnetic fields of free magnetic layers included in samples and MR ratios measured after heat treatment;

[0032]FIG. 13 is a table listing the coercive farces and saturation magnetic fields of a free magnetic layer and MR ratios in relation to different thicknesses of an alumina layer;

[0033]FIG. 14 is a table listing the coercive forces and saturation magnetic fields of free magnetic layers included in samples and MR ratios measured after heat treatment;

[0034] F FIG. 15 is a table listing the coercive forces and saturation magnetic fields of a free magnetic tayer and MR ratios in relation to diffusion control layers of different kinds;

[0035]FIG. 16 is a table listing the coercive forces and saturation is magnetic fields of free magnetic layers included in samples and MR ratios measured after heat treatment; and

[0036]FIGS. 17 and 18 are tables each listing the coercive forces and saturation magnetic fields of a free magnetic layer and MR ratios in relation to diffusion control layers of different kinds.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0037]FIGS. 1 and 2 show two different typical shield type devices to which the present invention is applied. The device shown in FIG. 1 includes a substrate 1. A lower shield layer 2, a lower gap layer 3 and MR effect element 6 sequentially laminated on the substrate 1. An insulating layer 7 for determining a gap may be formed on the MR effect element 6. as the case may be. The lower shield layer 2 is, in many cases, patterned in a suitable size by a photoresist (PR) step. The MR effect element 6 is also patterned in a suitable size by a PR step. A longitudinal bias layer 4 and a lower electrode layer 5 are sequentially formed in such a manner as to contact the edges of the MR effect element 6. An upper gap layer 8 and an upper shield layer 9 are sequentially laminated on the layers 4 and 5.

[0038] The device shown in FIG. 2 includes a lower shield layer 12, a lower gap layer 13 and an MReffect element16 sequentiIlly laminated on a substrate 11. The lower shield layer 12 is, in many cases, patterned in a suitable size by a PR step. The MR effect element 16 Is also patterned in a suitable size by a PR step, A longitudinal bias layer 14 and a lower electrode layer 15 are sequential ly formed in such a manner as to partly overlap the MR effect element 16. An upper gap layer 18 and an upper shield layer 19 are sequentially laminated on the layers 14 and 15.

[0039] For the lower shield layer 2 or 12, use may be made of, e.g., an NiFe, CoZr, CoFeB, CoZrMo, CpZrNb, CoZr. CoZrTa, CoHf, GoTa, CoTaHf, CoNbHf. CoZrNb, CoHfPd, CoTaZrNb or CoZrMoNi alloy, FeAlSi or iron nitride. The shield layer 2 or 12 should preferably be 0.3 μm to 10 μm thick.

[0040] The lower gap layer 3 or 13 may advantageously be formed of, e.g., alumina, SiO₂, aluminum nitride, silicon nitride or diamond-like carbon. The thickness of the lower gap layer 3 or 13 should preferably be 0.01 μm to 0.20 μm.

[0041] The lower electrode layer 5 or 15 may advantageously be formed of Zr, Ta or Mo or an alloy or a mixture thereof. The lower electrode layer 5 or 15 should preferably be 0.01 μm to 0.10 μm thick. For the longitudinol bias layer 4 or 14, use may be made of CoCrPt, CoCr, CoPt, CoCrTa, FeMn, NiMn, IrMn, PtPdMn, ReMn, PtMn, CrMn, Ni oxide. ion oxide, an Ni oxide and Co oxide mixture, an Ni oxide and Fe oxide mixture, an Ni oxide and Co oxide film or an Ni oxide and Fe oxide fiIm by way of example.

[0042] The insulating layer 7 for determining a gap may advantageousIy be formed of alumina, Si0 ₂, aluminum nitride, silicon nitride or diamond-like carbon and shouId preferably be 0.005 μm to 0.05 μm thick.

[0043] The upper gap layer 8 or 18 may be formed of alumina, SiO₂, aluminum nitride, silicon nitride or diamond-like carbon by way of example and should preferably be 0.01 μm to 0.20 μm thick.

[0044] Further, the upper shield layer 9 or 19 may be formed of, e.g., NiFe or CoZr or CoFeB, CoZrMo, CoZrNb, CoZr, CoZrTa, CoHf, CoTa, CoTaHf, CoNbHf, CoZrNb, CoHfPd, CoTaZrNb or CoZrMoNi alloy, FeAlSi or ion nitride. The thickness of the upper shield layer 1 or 9 should preferably be between 0.3 μm and 10 μm.

[0045] The shield type devices shown in FIGS. 1 and 2 each can implement a read/write head with an inductive coil forming a write head portion.

[0046]FIG. 3 shows a specific configuration of a read/write head. As shown, the read/write head is made up of a read head implemented by the MR effect element of the present invention and an interactive write head, While the MR effect element is combined with the write head adapted for longitudinal magnetic recording, it may be combi ned with a vertical write head used for vertical magnetic recording.

[0047] Specifically. the head shown in FIG. 3 has a slider or base 21. A read head is formed on the slider 21 and made up of an upper shield film 22, a lower shield film 23, an MR effect film 24. and an electrode film 25. A write head is formed on the read head and made up of an upper magnetic film 26, a lower magnetic film 27, and a coil 28, The upper shield film 22 of the read head and the lower magnetic film 27 of the write head may be implemented as a single magnetic film, if desired.

[0048] The read/write head with the above configuration selectively records signals in a magnetic recording medium or reproduces them from the recording medium. As shown in FIG. 3, the sensing portion of the read head and the magnetic gap of the write head lie one above the other and can therefore be positioned at the same track at the same time. After the slider has been machined, the readJarite head is mounted to a support member, provided with wirings, and then mounted to a magnetic recording/reproducing apparatus.

[0049]FIG. 4 shows a specific configuration of a recording/reproducing apparatus using the MR effect element of the present invention. As shown. anr MR effect film 32 and an electrode filIm 33 are formed on a base 31 playing the role of a head slider 30 at the same time. After the Lead slider 31 has been machinecd, it is provided with wirings and then mounted to the apparatus. A positioning mechanism, not shown, positions the head slider 30 at a preselected track formed on a magnetic recording medium 34.

[0050] A drive motor, not shown, causes the recording medium 34 to spin. The head slider 30 moves relative to the recording medium 34 at a height of 0.2 μm or more above the medium 34 or in contact with the medium 34. In this condition, the MR effect film 32 reads a magnetic signal out of the recording medium 34 in the form of a leakage magnetic field.

[0051] The MR element may have any one of the following different structures (1) through (6):

[0052] (1) substrate/Si layer/metal under layer/free magnetic layer/nonmagnetic layer/fixed magnetic layer/antiferromagnetic layer/protection layer;

[0053] (2) substrate/Si layer/metal under layer/free magnetic layer/first MR enhancing layer/nonmagnetic layer/fixed magnetic layer/fixing layer/protection layer;

[0054] (3) substrate/Si layer/metal under layer/free magnetic layer/first MR enhancing layer/normagnetic layer/second MR enhancing layerlffed magnetic layer/fixing layer/protection layer;

[0055] (4) substrate/Si layer/diffusion control foyer/metal under layer/free magnetic layer/nonmagnetic layer/fixed magnetic layer/antiferromagnetic layer/protection layer;

[0056] (5) substrate/Si layer/diffusion control layer/metal under layer/free magnetic layer/first MR enhancing layer/nonmagnetic layer/fixed magnetic layer/fixing layer/protection layer; and

[0057] (6) substrate/Si layer/diffusion control layer/metal under layer/free magnetic layer/first MR enhancing layer/nonmagnetic layer, second MR enhancing layer/fixed magnetic layer/fixing layer/protection layer

[0058] For the diffusion control layer, use may be made of Ta, Hf, Zr, W, Cr, Ti, Mo, Pt, Ni, Ir, Cu, Ag, Co, Zn, Ru, Rh, Re, Au, Os, Pd, Nb, V or similar metal, an oxide or a nitride of Si, Ta, Al, Ti, V, Cr, Mn, Hf, W, Mo, Ni, Zn or similar metal, a mixture of the ox ide and nitride, or a mixture or a laminate of the metal and oxide and nitride mixture.

[0059] The metal under layer may be implemented by one or more metals in the form of a single film or a laminate. Specifically, use may be made of a single film, a mixture film or a laminate consisting of Ta, Hf, Zr, W, Cr, Ti, Mo, Pt, Ni, Ir, Cu, Ag, Co, Zn, Ru, Rh, Re, Au, Os, Pd, Nb and V.

[0060] The free magnetic layer may be formed of NiFe, Cofe, NiFeCo, FeCo, CoFeB, CoZrMo, CoZrNb, CoZr, CoZrTa, CoHf, CoTa, CoTaHf, CoHbHf, CoZrNb, CoHfPd, CoTaZrNb or CoZrMoNi all oy or an amorphous magnetic substance. This layer should preferably be about 1 nm to 10 nm thick.

[0061] As for the nonmagnetic layer, there may be used Cu with or without about 1 at % to 20 at % of Ag added thereto. Cu with about 1 at % to 20 at % of Re added thereto or a Cu—Au alloy. The nonmagnetic layer should preferably be 2 nm to 4 nm thick.

[0062] The first and second MR enhancing layers each may be formed of Co, NiFeCo or FeCO, a CaFeB, CoZrMo, CoZrNb, CoZr, CoZrTa, CoHf, CaTa, CoTaHf, CoNbHf, CoZrNb, CoHfPd, CoTaZrNb or CoZrMoNi alloy, or an amorphous magnetic material and should preferably be about 0.5 nm to 5 nm thick.

[0063] When neither the first nor the second MR enhancing layer is present, the MR ratio decreases. However, the number of steps for fabrication is successfully reduced due to the absence of the MR enhancing layers. For the fixed magnetic layer, use nay be made of metal selected from a group of Co-, Ni- and Fe-based materials or an alloy or a laminate thereof. The fixed magnetic layer should preferably be about 1 nm to 50 nm thick.

[0064] The fixing layer may be implemented by FeMn, NiMn, IrMn, RhMn, PtPdMn, ReMn, PtMn, PtCrMn, CrMn, CrAl, TbCo, Ni oxide, Fe oxide, Ni oxide and Co oxide mixture, Ni oxide and Fe oxide mixture, laminate Ni oxide and Co oxide film, laminate Ni oxide and Fe oxide film, CoCr, CoCrPt, CoCrTa or PtCo.

[0065] As for the protection layer, use is made of metal oxide or nitride, an oxide and nitride mixture, or a laminate metal and oxide film, a laminate metal and nitride film, or a laminate metal and oxide and nitride mixture film. Other hopeful candidates are Ti, V, Cr, Co, Cu, Zn, Y, Zr, Mb, Mo, Tc, Ru, Rh, Pd, Ag, Hf, Ta, W, Re, Os, Ir, Pt or Au, or an oxide or a nitride selected from a group consisting of Si, Al, Ti and Ta or a mixture thereof, or a mixture of the above oxide, nitride or a mixture thereof and one element or an ally of two or more elements selected frain a group consisting of Ta, Hf, Zr, W, Cr, Ti, Mo, kPt, Hi, Ir, Cu, Ag, Co, Zn, Ru, Rh, Re, Au, Os, Pd, Nb, V and Y and implemented as a laminate film.

[0066] Examples of the present invention will be described hereinafter. First, for comparison, an MR effect film lacking an Si layer was produced. This MR film had a glass substrate/Ta (3 nm)/NiFe (6 nm) /CoFe (1 nm) /Cu (2.7 nm)/CoFe (3 nm) /FeMn (10 nm)/Ta (3 nm) structure. Magnetic fields different by 90 degrees from each other were respectively applied to the NiFe (6 nm)/CoFe (1 nm) portion and CoFe (3 nm)/FeMn (10 nm) portion at the time of film formation.

[0067] A magnetic field parallel to the magnetic field used to form the CoFe/FeMn portion was applied to the above MR effect film in order to measure an R-H loop. The measurement showed that the free magnetic layer had a coercive force of 1 Oe and a saturation magnetic field of 5 Oe. The MR ratio was measured to be 7%.

[0068] On the other hand, whiIe a magnetic field of 500 Oe parallel to the magnetic field used to form the CoFe/FeMn portion was applied to the comparative MR affect film, the film was heated at 270° C. for 5 hours in vacuum. As a result, the coercive force of the free magnetic layer increased to 2.5 Oe while the saturation magnetic field of the same decreased to 30 Oe. The increase in coercive force and the decrease in saturation magnetic field indicate that the anisotropy of the free magnetic layer noticeably rotated in the direction of application of the magnetic field during heat treatment. After the heat treatment, the MR ratio was found to be 6%.

[0069] An MR effect element with a glass substrate/Si (10 nm) /Ta (3 nm)/NiFe (6 nm)/CoFe (1 nm)/Cu (2.7 nm)/CoFe (3 nm) /FeMn (10 nm)/Ta (3 nm) structure was produced. Specifically, for the Si/Ta/NiFe/CoFe portion, a magnetic field of about 100 Oe was applied while the substrate temperature was varied. After the sufficient cooling of this portion, the Cu/CoFe/FeMn/Ta portion was formed.

[0070]FIG. 5 shows how the coercive force and saturation magnetic field of the free magnetic layer and the MR ratio varied in accordance with the substrate temperature. As shown, the coercive force and saturation magnetic field tended to increase as the substrate temperature rose although such a tendency was not clearly accounted for. The MR ratio slowly decreased with the elevation of substrate temperature up to 25o° C., but sharply fell at temperatures above 250° C.

[0071] The above MR effect film was subjected to a magnetic field of 500 Oe parallel to the magnetic field used to form the CoFe/FeMn portion and was heated at 270° C. (heat treatment temperature B hereinafter) for 5 hours. FIG. 6 tabulates the coercive forces and saturation magnetic fields of the free magnetic fayer subjected to the heat treatment temperature B and MR ratios. As shown, the coercive force decreased and the saturation magnetic field increased at substrate temperatures of 150° C. and above. It will be seen that by the heat treatment effected at temperatures of 150° C. and above, the rotation of the free magnetic layer in the direction of anisotropy and ascribable to the Si layer can be reduced.

[0072] An MR effect element with a glass substrate/Si (10 nm)/Ta (3 nm)/NiFe (6 nm)/CoFe (1 nm)/Cu (2.7 nm)/CoFe (3 nm)/FeMn (10 nm)/Ta (3 nm) structure was produced. After the formation of the Si/Ta/NiFe/CoFe portion, the laminate was heated in a magnetic field of about 100 Oe applied in the same direction as the magnetic field used for film formation. After the sufficient cooling of this portion, the Cu/CoFe/FeMn/Ta portion was formed.

[0073]FIG. 8 lists the coercive forces and saturation magnetic fields of the free magnetic layer subjected to the above treatment temperature Cheat treatment tenperature A hereinafter) and MR ratios. As shown, the coercive force and saturation magnetic field tended to increase with the elevation of heat treatment temperature A in the same manner as when the substrate temperature was varied. The MR ratio slowly decreases in accordance with the hs,at treatment temperature up to 250° C. but sharply fell at temperatures above 250° C.

[0074] A sample identical in configuration with the above MR effect element was heated at 270° C.(heat treatment temperature B) for 5 hours in a magnetic field of 500 Oe parallel to the magnetic field used to form the CoFe/FeMn portion. The resulting coercive forces and saturation magnetic fields of the free magnetic layer and MR ratios are listed in FIG. 9. As shown, at temperatures of 100° C. and above, the coercive force and saturation magnetic field of the free magnetic layer decreased and increased, respectively, It will be seen that at temperatures higher than 100° C. inclusive the rotation of the free magnetic layer in the direction of anisotropy and ascribable to the Si layer can be reduced.

[0075] An MR effect element with a glass substrate (10 nm)/alumina (10 nm)/Ta (3 nm) NiFe (5 nm) /CoFe (1 nm)/Cu (2.7 nm) /CoFe (3 nm)/FeMn (10 nm)/Ta (3 cm) structure was produced. Specifically, the Si/alumina/Ta/NiFe/CoFe portion was formed in a magnetic field of 100 Oe with the substrate temperature being varied. After the sufficient cooling of this portion, the Cu/CoFe/FeMn/Ta portion was formed. Magnetic fields different by 90 degrees from each other were respectively assigned to the NiFe (6 nm)/CoFe (1 nm) portion and CoFe (3 nm)/FeMn (10 nm) portion. FIG. 10 shows the coercive forces and saturation magnetic fields of the free magnetic layer and MR ratios in relation to various substrate temperatures. As shown, the coercive force and saturation magnetic field tended to slightly increase with the elevation of substrate temperature although such a tendency was not clearly accounted for. The MR ratio slowly decreased in accordance with the elevation of the substrate temperature up to 250° C. but rather sharply fell at temperatures above 250° C.

[0076] A sample identical in configuration with the above MR effect element was heated at 270° C. (heat treatment temperature B) for 5 hours in a magnetic field of 500 Oe parallel to the magnetic field used to form the CoFe (3 nm)/FeMn (10 nm) portion. FIG. 7 lists the resulting coercive forces and saturation magnetic fields of the free magnetic layer and MR ratios. As showm, at temperatures higher than 150° C. inclusive, the coercive force and saturation magnetic field of the free magnetic layer decreased and increased, respectively. It will be seen that at temperatures higher than 150° C. inclusive the rotat ion of the free magnetic layer in the direction of anisotropy layer and ascribable tb the Si layer/alumina layer can be reduced. Further, the lower limit of the substrate temperature capable of reducing the rotation of the free magnetic layer was higher when the alumina layer was present than when it was absent; the diffusion of Si from the Si layer to the Ta/NiFe/CoFe layer is slowed down.

[0077] An MR film with a glass substrate/Si (10 nm)/alumina (10 nm)/Ta (3 nm)/NiFe (6 nm)/CoFe (1 nm)/Cu (2.7 nm) /CoFe (3 nm)/FeMn (10 nm)/Ta (3 nm) structure was produced. After the formation of the Si/alumina/Ta/NiFe/CoFe portion, the laminate was heated in a magnetic field of about 100 Oe identical in direction with the magnetic field used for film formation. After the sufficient cooling of the above portion, the 0Cu/CoFe/FeMn/Ta portion was formed. Magnetic fields different by 90 degrees from each other were respectively assigned to the NiFe (6 nm)/CoFe (1 nm) portion and CoFe (3 nm)/FeMn (10 nm) portion. FIG. 11 shows the resulting coercive forces and saturation magnetic fields of the free magnetic layer and MR ratios in relation to various heat treatment temperatures A.

[0078] As shown in FIG. 11, the coercive force and saturation temperature tended to slightly increase with the elevation of the heat treatment temperature A although such a tendency was not clearly accounted for. The MR ratio slowly decreased in accordance with the elevation of the heat treatment temperature A up to 250° C., but rather sharply fell at temperatures above 150° C.

[0079] A sample having the same structure as the above film was heated at 270° C. (heat treatment temperature B) for 5 hours in a magnetic field of 500 Oe paralllel to the magnetic field used to form the CoFe/FeMn layer. FIG. 12 shows the resulting coercive forces and saturation magnetic fields of the free magnetic layer of the sample and MR ratos. As shown, at temperatures higher than 150° C. inclusive, the coercive force and saturation magnetic field decreased and increased, respectively. It will be seen that at temperatures above 150° C. the rotation of the free magnetic layer in the direction of anisotropy and ascribable to the Si layer/alumina layer can be reduced.

[0080] As also shown in FIG. 11, the lower limit of the heat treatment temperature A capable of reducing the rotation of the free magnetic layer was higher when the alumina layer was present than when it was absent; the diffusion of Si from the Si layer to the Ta/NiFe/CoFe layer was slowed down.

[0081] An MR effect film with a Cu (2.7 nm)/CoFe (3 nm)/FeMn (10 nm)/Ta (3 nm) structure was produced. Specifically, the Si/alumina/Ta/NiFe/CoFe portion was formed at a substrate temperature of 250° C. in a magnetic field of about 100 Oe and then sufficiently cooled off. Subsequently, the Cu/CoFe/FeMn/Ta portion was formed. in this case, the heat treatment temperature A was 250° C. Magnetic fields different by 90 degrees from each other were respectively assigned to the NiFe (6 nm)/CoFe (1 nm) portion and CoFe (3 nm)/FeMn (10 nm) portion. The coercive forces and saturation magnetic fields of the free magnetic layer are listed in FIG. 13 in relation to various thicknesses of the alumina layer. As shown, the coercive force and saturation magnetic field of the free magnetic layer and MR ratio are little dependent on the thickness of the alumina layer.

[0082] A sample identical in structure with the above sample was heated at 270° C.(heat treatment temperature B) for 5 hours in a magnetic field of 500 Oe parallel to the magnetic field used to form the CoFe/FeMn layer. FIG. 14 shows the resulting coercive forces and saturation magnetic fields of the free magnetic layer and MR ratios. As shown, the coercive force and saturation magnetic field increased and decreased, respectively, with an increase in the thickness of the alumina layer which played the role of a diffusion control layer. Presumably, the diffusion of Si from the Si layer to the Ta under layer and to the NiFe/CoFe layer via the alumina layer was greater in amount when the alumina layer was thinner, enhancing the thermal stability of the NiFe/CoFe layer as to induced magnetic anisotropy. The MR ratio decreased with an increase inthe thickness of the alumina layer. This is presumably because a thinner alumina layer results in excessive diffusion of Si to the NiFe/CoFe layer and therefore in a decrease in MR ratio at the interface between CoFe and Cu.

[0083] An MR element with a glass substrate/Si (10 nm)/diffusion control layer (10 nm)/Ta (3 nm)/NiFe (6 nm)/CoFe (1 nm)Cu (2.7 nm)/CoFe (3 nm)/FeMn (10 nm)/Ta (3 nm) was produced. Specifically, the Si/alumina/Ta/NiFe/CoFe portion was formed with the substrate being heated at 250° C. in a magnetic field of about 100 Oe. After the sufficient cooling of this portion, the Cu/CoFe/FeMnTa portion was formed. The heat treatment temperature A was selected to be 250° C. Magnetic fields different by 90 degrees from each other were respectively assigned to the NiFe (6 nm)/CoFe (1 nm) portion and CoFe (3 nm)/FeMn (10 nm) portion.

[0084]FIG. 15 shows the resulting coercive forces and saturation magnetic fields of the free magnetic layer and MR ratios in relation to various kinds of diffusio i control layers. As shown, the coercive force and saturation magnetic field of the above sample remained substantially constant without regard to the kind of the diffusion control layer.

[0085] A sample identical in structure with the above sample was heated at 270° C. (heat treatment temperature B) for 5 hours in a magnetic field parallel to the magnetic field used to form the CoFe/FeMn layer. FIG. 16 shows the resulting coercive forces and saturation magnetic fields of the free magnetic layer and MR ratios. As shown, the coercive force and saturation magnetic field remain substantially constant without regard to the kind of the diffusion control layer. This indicates that the anisotropy of the free magnetic layer was fixed in the direction occurred just after the film formation, and that the 270° C. (heat treatment temperature B) 5 hours heat treatment effected in the magnetic field of 500 Oe did not cause the anisotropy to rotate.

[0086] The above condition is presumably because Si reached the Ta under layer via the diffusion control layer. However, the MR ratio was scattered in the range of from 4.9% to 5.2%. This is presumably because the amount of Si reached the interface between the free magnetic layer and the nonmagnetic layer was dependent on the kind of the diffusion control layer.

[0087] An MR effect film with a Ta (3 nm)/NiFe (6 nm)/CoFe (1 nm)/Cu (2.7 nm) /CoFe (3 nm) structure directly formed on a g lass substrate and an MR effect film with the same structure, but formed via an Si (10 nm)/alIumina (1 nm) layer, were produced. Specifically, to form the Ta/NiFe/CoFe layer, the substrate was heated at 250° C. in a magnetic field of about 100 Oe. After the sufficient cooling of this layer, the Cu/CoFe/FeMn/Ta layer was formed. Magnetic fields different by 90 degrees from each other were respectively applied to the NiFe (6 film)/Co (1 nm) /Cu (2.7 nm) portion and CoFe (3 nm)/FeMn (10 nm) portion. The resulting MR film was heated at the heat treatment temperature B in a magnetic field of 500 Oe parallel to the magnetic field used to form the CoFe/FeMn layer.

[0088] The temperature and duration of heat treatment for fixing the magnetization of the fixed layer depend on the kind of the fixing layer. Therefore, as shown in FIGS, 17 and 18, the heat treatment temperature B and duration thereof were varied in accordance with the kind of the fixing layer. The heat treatment may be needless or the heat treatment temperature may be low, depending on the kind of the fixing layer. However, for both of the two different configurations, heat treatment was effected at 230° C. for 3 hours or more for the formation of the MR effect film on a head. The resulting coercive forces and saturation magnetic fields of the free magnetic layers and MR ratios are shown in FIGS. 17 and 18.

[0089] As FIG. 17 indicates, the free magnetic layer had a coercive force greater than 1.5 Oe without regard to the preserce/absence of the Si/alumina layer. This is presumably because the heat treatment at the temperature B caused an induced magnetic anisotropy applied to the free magnetic layer at the time of film formation to bend in the direction of the magnetic field for heat treatment. As FIG. 18 indicates, as for all of the different kinds of fixing layers, the coercive force of the free magnetic layer is smaller when the Si/alumina layer is present than when it is absent. This suggests that Si was effectively diffused into the NiFe/CoFe layer, As for some materials including CoCr, the free magnetic layer has a coercive force as high as 1.8 Oe to 2.4 Oe. This is presumably ascribable to some cause other than the rotation of the anisotropy, because the saturation magnetic field of the froe magnetic field is also high.

[0090] Hereinafter will be described Examples of the present invention applied to the shield type devices and each effecting particular heat treatmernt, together with the results of evaluation as magnetic heads.

EXAMPLE 1

[0091] A shield type device having the configuration shown in FIG. 1 was produced and included an NiFe lower shield layer and an alumina lower gap layer. For an MR effect film, use was made of an Si (10 nm)/alumina (10 nm)/Ta (3 nm)/Ni₆₂Fe₁₈ (4 nm)/Co₉₀Fe₁₀ (1 nm)/Cu (2.7 nm)/Co₉₀Fe₁₀ (2 nm)/Ni₈₂Fe₁₈ (1 nm)/Ni₄₅Mn₅₄ (30 nm)/Ta (3 nm) structure. The Ta/NiFe/CoFe layer was formed at the substrate temperature of 250° C. in a magnetic field of 100 Oe. The other layers were formed without heating the substrate. After the formation of the MR effect film, the film was heated at 270° C. for 5 hours in a magnetic field of 500 Oe perpendicular to the above magnetic field.

[0092] The MR effect film was patterned in the size of 1×1 μm by a PR step to produce an MR effect element. A CoCrPt anid an Mo lower electrode layer were laminated on the MR effect element in such a manner as to contact the edges of the element. An upper gap layer and an upper shield layer were implemented by alumina and NiFe, respectively.

[0093] The above head was provided with the configuration of FIG. 3, subjected to slider machining, and then used to record and reproduce data from a CoCrTa recording medium. Therecording medium had a write track width of 1.5 m, a write gap of 0.2 m, a read track width of 1.0 m, and a read gap of 0.21 m. As for the write head, a photoresist curing step for forming a coil portion was effected at 250° C. for 2 hours.

[0094] As a result of the photoresist curing step, the magnetization direction of the fixed layer and that of the fixing layer expected to be oriented in the direction of height of the device rotated and prevented the function of a spin valve from being attained. To achieve the function of a spin valve, after the formation of the read head portion and write head portion, the above structure was heated at 200° C. for 1 hour in a magnetic field of 500 Oe for magnetization. The resulting magnetization curve showed little rotation of the easy axis of the free magnetic layer in the direction of magnetization. The recording medium had a coercive force of 2.5 kOe, and the reproduction output was measured by varying the length of a record mark.

[0095] The above measurement showed that the mark length halving the reproduction output was 154 kFIC, that the reproduction output (peak-to-peak) was 1.7 mV, that an S/N (Signal-to-Noise) ratio was 27 dB, that the error rate was less than 10⁻⁶ inclusive, that no noise occurred, and that the waveform was desirable. An environment test effected at 80° C. for 2,500 hours with 500 Oe did not cause the above error rate to change. Further, a current feed test effected with a current density of 2×10⁷ A/cm² in an environent of 80° C. did not cause the resistance or the MR ratio to change up to 1,000 hours.

EXAMPLE 2

[0096] A shield type device, having the configuration shown in FIG. 1 was produced and included an NiFe lower shield layer and an alumina lower gap layer. For an MR effect film, use was made of an Si (10 nm)/alumina (10 nm)/Ta (3 nm) /Ni₆₂FeA₁₈ (4 nm)/Co₉₀Fe₁₀ (1 nm)/Cu (2.7 nm)/Co₉₀Fe₁₀ (2 nm) /Ni₆₂Fe₁₈ (1 nm) /Ni₄₅Fe₅₄ (30 nm)/Ta (3 nm) structure. The Ta/NiFe/CoFe layer was formed at the substrate temperature of 250° C. in a magnetic field of 100 Oe. The other layers were formed without heating the substrate. After the formation of the MR effect film, the film was heated at 25° C. for 5 hours in a magnetic field of 500 Oe perpendicular to the above magnetic field.

[0097] The MR effect film was patterned in the size of 1×1 μm by a PR step to produce an MR effect element. A CoCrPt ard an Mo lower electrode layer were laminated on the MR film in such e manner as to contact the edges of the fi m. An upper gap layer and an upper shield layer were implemented by alumina and NiFe, respectively.

[0098] The above head was provided with the configuration of FIG. 3. subjected to sl ider machining, and then used to record and reproduce data from a CoCrTa recording medium. The recording medium had a write track width of 1.5 m, a write gap of 0.2 m, a read track width of 1.0 m, a and a read gap of 0.21 m. As for the write head, a photoresist curing step for forming a coil portion was effected at 250° C. for 2 hours.

[0099] As a result of the photoresist curing step, the ragnetization direction of the fixes layer and that of the fixing layer expected to be oriented in the directiNr of height of the device rotated and prevented the function of a spin valve from being attained. To achieve the function of a spin valve, after the formation of the read head portion and write head portion, the above structure was heated at 200° C. for 1 hour in a magnetic field of 500 Oe for magnetization. The resulting magnetization curve showed little rotation of the easy axis of the free magnetic layer in the direction of magnetization. The recording medium had a coercive force of 2.5 kOe, and the reproduction output was measured by varying the length of a record mark.

[0100] The above measurement showed that the mark length ha I ving the reproduction output was 154 kFCI, that the reproduction output (peak-to-peak) was 1.8 mV, that an S/N ratio was 26.9 dB, that the error rate was less than 10⁻⁶ inclusive, that no noise occurred, and that the waveform ws desirable. An environment test effected at 80° C. for 2,500 hours with 500 Oe did notcausethe above error rate to change. Further, a current feed test effected with a current density of 2×10⁷ A/cm² in an environment of 80° C. did not cause the resistance or the MR ratio to change up to 1,000 hours.

EXAMPLE 3

[0101] A shield type device having the configuration shown in FIG. 1 was produced and included an NiFe lower shield layer and an alumina lower gap layer. For an MR effect film, use was made of an Si (10 nm)/alumina (10 nm)/Ta (3 nm)/Ni₈₂Fe₁₈ (4 nm)/Co₉₀Fe₁₀ (1 nm)/Cu (2.7 nm)/Co₉₀Fe₁₀ (2 nm)/Ni₈₂Fe₁₈ (1 nm)/IR₂₄Mn₇₆ (10 nm)/Ta (3 nm) structure. The Ta/NiFe/CoFe layer was formed at the substrate temperature of 270° C. in a magnetic field of 100 Oe. The other layers were formed without heating the substrate. After the formation of the MR effect film, the film was heated at 250° C. for 5 hours in a magnetic field of 500 Oe perpendicular to the above magnetic field.

[0102] The MR effect film was patterned in the size of 1×1 μm by a PR step to produce an MR effect element. A CoCrPt and an Mo lower electrode layer were laminated on the MR effect element in such a manner as to contact the edges of the element. An upper gap layer and an upper shield layer were implemented by alumina and NiFe, respectively.

[0103] The above head was provided with the configuration of FIG. 3, subjected to slider machining, and then used to record and reproduce data from a CoCrTa recording medium. The recording medium had a write track width of 1.5 m, a write gap of 0.2 m, a read track width of 1.0 m, and a read gap of 0.21 m. As for the write head, a photoresist curing step for farming a coil portion was effected at 250° C. for 2 hours.

[0104] As a result of the photoresist curing step, the magnetization direction of the fixed layer and that of the fixing layer expected to be oriented in the direction of height of the device rotated and prevented the function of a spin valve from being attained. To achieve the function of a spin valve. after the formation of the read head portion and write head portion, the above structure was heated at 200° C. for 1 hour in a magnetic field of 500 Oe for magnetization. The resulting magnetization curve showed little rotation of the easy axis of the free magnetic layer in the direction of mragnetization. The recording medium had a coercive force of 2.5 kOe, and the reproduction output was measured by varying the length of a record mark.

[0105] The above measurement showed that the mark length halving the reproduction output was 146 KFCI, that the reproduction output (peak-to-peak) was 1.7 mV, that an S/N ratio was 26.5 dB, that the error rate was less than 10⁻⁶ inclusive, that no noise occurred, and that the waveform was desirable. An environment test effected at 80° C. for 2,500 hours with 5 Oe did not cause the above error rate to change. Further, a current feed test effected with a current density of 2×10⁷ A/cm² in an environment of 80° C. did not cause the resistance or the MR ratio to change up to 1,000 hours.

[0106] A shield type device having the configuration shown in FIG. 1 was produced and included an NiFe lower shield layer and an alumina lower gap layer. For an MR effect film, use was made of an Si (10 nm)/CiO₂ (10 nm)/Ta (3 nm)/Ni₆₂Fe₁₈ (4 nm)/Co₉₀Fe₁₀ (1 nm)/Cu (2.7 nm)/Co₉₀Fe₁₀ (2 nm)/Ni₈₂Fe₁₈ (1 nm)/Fe₂O₃(1 nm)/NiO (30 nm)/Ta (3 nm) structure. In this case, the substrate was not heated at all. A magnetic field for film formation was selected to be 100 Oe. After the film formation, the film was heated at 270° C. for 5 hours in a magnetic field of 500 Oe perpendicular to the above magnetic field.

[0107] The MR effect film was patterned in the size of 1×1 μm by a PR step to produce an MR effect element. A CoCrPt and an Mo lower electrode layer were laminated on the MR effect element in such a manner as to contact the edges of the element An upper gap layer and an upper shield layer were implewented by alumina and NiFe. respectively.

[0108] The above head was provided with the configuration of FIG. 3, subjected to slider machining, and then used to record and reproduce data from a CoCrTa recording medium. The record ingmedi um had a write track width of 1.5 m, a write gap of 0.2 m, a read track width of 1.0 m, and a read gap of 0.21 m. As for the write head, a photoresist curing step for forming a coil portion was effected at 250° C. for 2 hours.

[0109] As a result of the photoresi st curing step, the magnetization direction of the fixed layer Eind that of the fixing layer expected to be oriented in the d irection of height of the device rotated and prevented the function of a sipin valve from being attained. To achieve the function of a spin valve, after the format ion of the read head portion and write head portion, the above structure was heated at 20° C. for 1 hour in a magnetic field of 500 Oe for meignatization. The resulting magnetization curve showed little rotation of the easy axis of the free magnetic layer in the direction of magnetization. The recording medium had a coercive force of 2.5 kOe, and the reproduction output was measured by varying the length of a record mark.

[0110] The above measurement showed that the mark length halving the reproduction output was 160 KFCI, that the reproduction output (peak-to-peak) was 2.1 mV, that an S/N ratio was 28.5 dB, that the error rate was less than 10⁻⁶ inclusive, that no noise occurred, and that the waveform was desirable. An environment test effected at 80° C. for 2,500 hours with 500 Oe did not cause the above error rate to change. Further, a current feed test effected with a current density of 2×10⁷ A/cm² in an environment of 80° C. did not cause the resistance or the MR ratio to change up to 1,000 hours.

EXAMPLE 6

[0111] A shield type device having the configuration shown in FIG. 1 was produced and included an NiFe lower shield layer and an alumina lower gap layer. For an MR effect film, use was made of an Si (10 nm)/SiO₂ (10 nm)/Ta (3 nm)/Ni₈₂Fe₁₈, (4 nm)/Co₉₀Fe₁₀ (1 nm)/Cu (2.7 nm)/Co₉₀Fe₁₀ (2 nm)Ni₈₂Fe₁₈ (1 nm)/CoO (1 nm)/NiO (30 nm)/ Ta (3 nm) structure. The substrate was not heated at all during film formation. A magnetic field for film fornmtion was selected to be 100 Oe. After the film formation, the film was heated at 270° C. for 5 hours in a magnetic field of 500 Oe perpendicular to the above maegnetic field.

[0112] The MR effect film was patterned in the size of 1×1 μm by a PR step to produce an MR effect element. A CoCrPt and an Mo lower electrode layer were laminated on the MR effect element in such a manner as to contact the edgeis of the element. An upper gap layer and an upper shield layer were implemented by alumina and NiFe, respectively.

[0113] The above head was provided with the configuration of FIG. 3, subjected to slider machining, and then used to record and reproduce data from a CoCrTa recording medium, The recording medium had a write track width of 1.5 m, a write gap of 0.2 m, a read track width of 1.0 m, and a read gap of 0.21 m. As for the write head, a photoresist curing step for forming a coil portion was effected at 250° C. for 2 hours.

[0114] As a result of the photoresist curing step, the magnetization direction of the fixed layer and that of the fixing layer expected to be oriented in the direction of height of the device rotated and prevented the function of a spin valve from being attained. To achieve the function of a spin valve, after the formation of the read head portion and write head portion, the above structure was heated at 200° C. for 1 hour in a magnetic field of 500 Oe for magnetization. The resulting magnetization curve showed little rotation of the easy axis of the free magnetic layer in the direction of magnetization. The recording medium had a coercive force of 2.5 kOe, and the reproduction output was measured by varying the length of a record mark.

[0115] The above measurement showed that the mark length halving the reproduction output was 161 kFCI, that the reproduction output (peak-to-peak) was 2.0 mV, that an S/N ratio was 28.1 dB, that the error rate was less then 10⁻⁶ inclusive, that no noise occurred, and that the waveform was desirable. An environment test effected at 80° C. for 2,500 hours with 500 Oe did not cause the above error rate to change. Further, a current feed test effected with a current density of 2×10⁷ A/cm² in an environment of 80° C. did not cause the resistance or the MR ratio to change up to 1,000 hours.

EXAMPLE 6

[0116] A shield type device having the configuration shown in FIG. 1 was produced and included an NiFe lower shield layer and an alumina lower gap layer. For an MR effect film, use was made of an Si (10 nm)/alumina (12 nm)/Ta (3 nm)/Ni₈₂Fe₁₈ (4 nm)/Co₉₀Fe₁₀ (1 nm)/Cu (2.7 nm)/Co₉₀Fe₁₀ (2 nm)/Ni₈₂Fe₁₈ (1 nm)/Ni₄₆Mn₅₄ (30 nm/Ta (3 nm) structure. The a Ta/NiFe/CoFe layer was formed with the substrate being heated at 250° C. while the other films were formed without the substrate being heated. A magnetic field for film format ion was seI ected to be 100 Oe. After the film formation, the film was heated at 270° C. for 5 hours in a magnetic field of 500 Oe perpendicular to the above magnetic field.

[0117] The MR effect film was patterned in the size of 1×1 μm by a PR step to produce an MR effect ellement. A CoCrPt ard an Mo lower electrode layer were laminated on the MR effect element in such a manner as to contact the edges of the element. An upper gap layer and an upper shield layer were implemented by alumina and NiFe, respectively.

[0118] The above head was provided with the configuration of FIG. 3, subjected to slider machining, and then used to record and reproduce data froma CoCrTa recording medium. The recording medium had a write track width of 1.5 m, a write gap of 0.2 m, a read track width of 1.0 m, and a read gap of 0.21 m. As for the write head, a photoresist curing step far forming a coil portion was effected at 250° C. for 2 hours.

[0119] As a result of the photoresist curing step, the magnetization direction of the fixed layer and that of the fixing layer expected to be oriented in the direction of height of the device rotated and prevented the function of a spin valve from being attained. To achieve the function of a spin valve, after the formation of the read head portion and write head portion, the above structure was heated at 200° C. for 1 hour in a magnetic field of 500 Oe for magnetization. The resulting magnetization curve showed little rotation of the easy axis of the free magnetic layer in the direction of magnetization. The recording medium had a coercive force of 2.5 kOe, and the reproduction output was measured by varying the length of a record mark.

[0120] The above measurement showed that the mark length halving the reproduction output was 157 kFCI. that the reproduction output (peak-to-peak) was 1.8 mV, that an S/N ratio was 26.9 dB, that the error rate was less than IVe inclusive, that no noise occurred, and that the waveform was desirable. An environment test effected at 80° C. for 2,500 hours with 500 Oe did not cause the above error rate to change. Further, a current feed test effected with a current dernsity of 2×10⁷ A/cm² in an environment of 80° C. did not cause the resistance or the MR ratio to change up to 1,000 hours.

EXAMPLE 7

[0121] A shield type device having the configuration shown in FIG. 1 was produced and included an NiFe lower shield layer and an alumina lower gap layer. For an MR effect film, use was made of an Si (10 nm)/SiO₂ (10 nm)/Ta (3 nm)/Ni₈₂Fe₁₈ (4 nm)/Co₉₀Fe₁₀ (1 nm)/Cu (2.7 nm)/Co₉₀Fe₁₀ (2 nm)/Ni₈₂Fe₁₈ (1 nm)/Ni₄₅Mn₆₄ (30 nm)/Ta (3 nm) structure. The Ta/NiFe/CoFe layer was formed with the substrate being heated at 250° C. while the other films were formed without the substrate being heated. A magnetic field for film formation was selected to be 100 Oe. After the film formation, the film was heated at 270° C. for 5 hours in a magnetic field of 500 Oe perpendicular to the above magnetic field.

[0122] The MR effect film was patterned in the size of 1 x I p m by a PR step to produce an MR effect clement. A CoCrPt and an Mo lower electrode layer were laminated on the MR effect element in such a manner as to contact the edges of the element- An upier gap layer and an upper shield layer were implemented by alumina and NiFe, respectively.

[0123] The above head was provided with the configuration of FIG. 3, subjected to slider machining, and then used to record and reproduce data from aCoCrTa recordingmedium. The recordingmedium had awrite to track width of 1.5 m, a write gap of 0.2 m, a read track width of 1.0 m, and a read gap of 0.21 m. As for the write head, a photoresist curing step for forming a coil portion was effected at 250° C. for 2 hours.

[0124] As a resuIt of the photoresist curing step, the magnetization direction of the fixed layer and that of the fixing layer expected to be oriented in the direction of height of the device rotated and prevented the function of a spin valve from being attained. To achieve the function of a spin valve, after the formation of the read head portion and write head portion, the above structure was heated at 200° C. for 1 hour in a magnetic field of 500 Oe for magnetization. The resulting magnetization curve showed little ratat ion of the easy axisof the free magnetic layer in the direction of magnetization. The recording medium had a coercive force of 2.5 kOe, and the reproduction output was measured by varying the length of a record mark.

[0125] The above measurement showed that the mark length halving the reproduction output was 159 kFCI, that the reproduction output (peak-to-peak) was 1.8 mV, that an S/N ratio was 26.8 dB, that the error-rate was fess than 10⁻⁶ inclusive, that no noise occurred, and that the waveform was desirable. An environiment test effected at 80° C. for 2,500 hours with 500 Oe did not cause the above error rate to change. Further, a current feed test effected with a current density of 2×10⁷ A/cm² in an environment of 80° C. did not cause the resistance or the MR ratio to change up to 11,000 hours.

EXAMPLE 8

[0126] A shield type device having the configuration shown in FIG. 1 was produced and included an NiFe lower shieId layer and an alumina lower gap layer. For an MR effect film, use was made of an Si (10 nm)/tantalum oxide (13 nm)/Ta (3 nm)/Ni₈₂Fe₁₈ (4 nm)/Co₉₀Fe₁₀ (1 nm)/Cu (2.7 nm)/Ni₈₂Fe₁₈ (1 nm)/Ni₄₈Mn₅₄ (30 nm)/Ta (3 nm) struture. The Ta/NiFe/CoFe layer was formed with the substrate being heated at 250° C. while the other films were formed without the substrate being heated. A magnetic field for film formation was selected to be 100 Oe. After the film formation, the film was heated at 270° C. for 5 hours in a magnetic field of 500 Oe perpendicular to the above magnetic field.

[0127] The MR effect film was patterned in the size of 1×1 μm by a PR step to produce an MR effect element. A CoCrPt and an Mo lower electrode layer were laminated on the MR effect element in such a manner as to contact the edges of the element, An upper gap layer hours.

[0128] As a result of the phtotresist curing step, the magnetization direction of the fixed layer and that of the fixing layer expected to be oriented in the direction of height of the device rotated and prevented the function of a spin valve from being attained. To achieve the function of a spin valve, after the formation of the read head portion and write head portion, the above structure was heated at 200° C. for 1 hour in a magnetic field of 500 Oe for magnetization. The resulting magnetization curve showed little rotation of the easy axi s of the free magnetic layer in the direction of magnetization. The recording medium had a coercive force of 2.5 kOe, and the reproduction output was measured by varying the length of a record mark.

[0129] The above measurement showed that the mark length halving the reproduction output was 156 kFCI, that the reproduction output (peak-to-peak) was 1.9 mV, that an S/N ratio was 26.7 dB, that the error rate was less than 10⁻⁶ inclusive, that no noise occurred, and that the waveform was desirable. An environment test effected at 80° C. for 2,500 hours with 500 Oe did not cause the above error rate to change. Further, a current feed test effected with a current density of 2×10⁷ A/cm² in an environment of 80° C. did not cause the resistance or the MR ratio to change up to 1,000 hours.

EXAMPLE 11

[0130] A shield type device having the configuration shown in FIG. 1 was produced and included an NiFe lower shield layer and an alumina mark.

[0131] The above measurement showed that the mark length halving the reproduction output was 155 kFCI, that the reproduction output (peak-to-peak) was 1.9 mV, that an S/N ratio was 26.8 dB, that the error rate was less than 10⁻⁶ inclusive, that no noise occurred, and that the waveform was dcirable. An environmerit test effected at 80SC for 2,500 hours with 500 Oe did not cause the above error rate to change. Further, a current feed test effected with a current density of 2×10⁷ Acm² in an envirounmerrt of 80° C. did not cause the resistance or the MR ratio to change up to 1,000 hours.

[0132] An experimental magnetic disk drive implemented by the present invention is as fol lows. Three recording media are amounted on a base included in thediskdrive. Ahead drivecircuit. asignal processing circuit and an input/output interface are mounted on the rear of the base. The disk drive is connected to the cutside by a thirty-two bits bus line.

[0133] A single magnetic heed faces one surface of each recording medium. A rotary actuator for driving such heads, a circuit for driving and controlling the roatary actuator, and a spindle motor for causing the recording media to spin are mounted on the disk drive. Each recording medium has a diameter of 40 mm and is capable of rdcording data over Its area tietween the diameter of 10 mm and the diameter of 40 mm. The disk drive uses a buried servo system for positioning each head and therefore implements a high density.

[0134] The above disk drive is directly connectable to a small size by computer as an outside storage. The input/output interface includes a cache memory and adapts itself to a bus line whose transfer rate ranges from 5 megabytes to 20 megabytes per second. Further, a plurality of such disk drives may be connected together to constitute a large capacity disk drive if an outside controller (disc controller) is available.

[0135] In summary, it will be seen that the present invention provides an MIR effect element including a free magnetic layer whose coercive force is small, and having an R-H loop involving a minimum of hysteresis, a method of producing such an MR effect element, and an MR sensor, an MR sensing system and a magnetic storage system each using the above MR effect element.

[0136] Various modifications will become possible for those skilled in the art after receiving the teachings of the present disclosure without departing from the scope thereof. 

What is claimed is:
 1. In an MR (Magneto Resistance) effect element, a laminate film is implemented by a unit consisting of an Si layer, a metal lower layer, a free magnetic layer, a nonmagnetic layer, a fixed layer, and a magnetic fixing layer.
 2. In an MR effect eleIent, a laminate film is implemented by a unit consisting of an Si layer, a diffusion control layer, a metal lower layer, a free magnetic layer, a nonmagnetic layer, a fixed layer, and a magnetic fixing layer.
 3. An MR effect element as claimed in claim 2 , wherein said diffusion control fayer comprises one of Ta, Hf, Zr, W, Cr, Ti, Mo, Pt, Ni, Ir, Cu, Ag, Co, Zn, Ru, Rh, Re, Au, Os, Pd, Mb and V.
 4. An MR effect element as claimed in claim 2 , wherein said diffusion control layer comprises one of an oxide and a nitride of Si, Ta, Al, Ti, V, Cr, Mn, Hf, Zr, W, Mo, Ni and Zn and a mixture of said oxide and said nitride.
 5. An MR effect element as claimed in claim 2 , wherein said diffusion control layer comprises one of a mixture and a raminate of an oxide and a nitride of Si, Ta, Al, Ti, V, Cr, Mn, Hf, Zr, W, Mo, Ni and Zn.
 6. A method of producing an MR effect element, comprising the steps of: sequentially forming an Si layer, a metal under layer and a free magnetic layer on a substrate; heating a resulting lamniate at a temperature between 100° C. and 400° C. in vacuum; and sequentially forming a nonmagnetic layer, a magnetic fixed layer, and a magnetic fixing layer.
 7. A method of producing an MR effect element, comprising the steps of: sequentially forming an Si layer, a diffusion control layer, a metal under layer and a free magnetic layer on a substrate; heating a resulting laminate at a temperature between 100° C. and 400° C. in vacuum; and sequentially forming a nonmagnetic layer, a magnetic fixed layer, and a magnetic fixing layer.
 8. A method as clainmd in claim 7 , wherein said diffusion control layer comprises Ta, Hf, Zr, W, Cr, Ti, Mo, Pt, Ni, Ir, Cu, Ag, Co, Zn, Ru, Rh, Re, Au, Os, Pd, Nb and V.
 9. An MR effect element as claimed in claim 7 , wherein said diffusion control layer comprises one of an oxide and a nitride of Si, Ta, Al, Ti, V, Cr, Mn, Hf, Zr, W, Mo, Ni and Zn and a mixture of said oxide and said nitride.
 10. An MR effect element as claimed in claim 7 , wherein said diffusion control layer comprises one of a mixture and a laminate of an oxide and a nitride of Si, Ta, Al, Ti, V, Cr, Mn, Hf, Zr, W, Mo, Ni and Zn.
 11. A method of producing an MR effect element, comprising the steps of: heating, at a time of sequentially forming an Si layer, a metal under layer and a free magnetic layer on a substrate, said substrate at a temperature between 100° C. and 400° C.; and sequentially forming a nonmagnetic layer, a magnetic fixed layer, and a magnetic fixing layer.
 12. A method of producing an MR effect element, comprising the steps of: heating, at a time of sequentially forming an Si layer, a diffusion control layer, a metal under layer and a free magnetic layer on a substrate, said substrate at a temperature between 100° C. and 400° C.; and sequentially forming a nonmagnetic layer, a magnetic fixed layer, and a magnetic fixing layer.
 13. A method as claimed in claim 12 , wherein said diffusion control layer comprises Ta, Hf, Zr, W, Cr, Ti, Mo, Pt, Ni, Ir, Cu, Ag, Co, Zn, Ru, Rh, Re, Au, Os, Pd, Nb and V.
 14. An MR effect element as claimed in claim 12 , wherein said diffusion control layer comprises one of an oxide and a nitride of Si, Ta, Al, Ti, V, Cr, Mn, Hf, Zr, W, Mo, Ni and Zn and a mixture of said oxide and said nitride.
 15. An MR effect element as claimed in claim 12 , wherein said diffusion control layer oonprises one of a mixture and a laminate of an oxide and a nitride of Si, Ta, Al, Ti, V, Cr, Mn, Hf, Zr, W, Mo, Ni and Zn.
 16. In an MR effect sensor, a lower shield layer, a lower gap layer and an MR effect element are laminated on a substrate, said shield layer and said MR effect element each being patterned, a longitudinal bias layer and a lower electrode layer are sequentially laminated in such a manner as to contact edges of said MR effect element, and an upper gap layer and an upper shield layer are sequentially laminated on said longitudinal bias layer and said lower electrode layer.
 17. An MR effect sensor as claimed in claim 16 , wherein said MR effect element comprises a laminate film implemented by a unit consisting of an Si layer, a metal lower layer, a free magnetic layer, a nonmagnetic layer, a fixed layer, and a magnetic fixing layer.
 18. An MR effect sensor as claimed in claim 16 , wherein said MR effect element comprises a laminate film implemented by a unit consisting of an Si layer, a diffusion control layer, a metal lower layer, a free magnetic layer, a nonmagnetic layer, a fixed layer, and a magnetic fixing layer.
 19. An MR effect sensor as claimed in claim 18 , wherein said diffusion control layer coiprises one of Ta, Hf, Zr, W, Cr, Ti, Mo, Pt, Ni, Ir, Cu, Ag, Co, Zn, Ru, Rh, Re, Au, Os, Pd, Nb and V.
 20. An IR effect element as claimed in claim 18 , wherein said diffusion control layer comprises one of an oxide and a nitride of Si, Ta, Al, Ti, V, Cr, Mn, Hf, Zr, W, Mo, Ni and Zn and a mixture of said oxide and said nitride.
 21. An MR effect element as claimed in claim 18 , wherein said diffusion control fayer comprises one of a mixture and a laminate of an oxide and a nitride of Si, Ta, Al, Ti, V, Cr, Mn, Hf, Zr, W, Mo, Ni and Zn.
 22. In an MR effect sensor, a lower shield layer, a lower gap layer and an MR effect element are laminated on a substrate, said shield layer and said MR effect element each being patterned, a longitudinal bias layer and a lower electrode layer are sequentially laminated in such a manner as to partly overlap said MR effect element, and an upper gap layer and an upper shield layer are sequentially laminated on said longitudinal bias layer and said lower electrode layer.
 23. An MR effect sensor as claimed in claim 22 , wherein said MR effect element comprises a laminate film implemented by a unit consisting of an Si layer, a metal lower layer, a free magnetic layer, a nonmagnetic layer, a fixed layer, and a magnetic fixing layer.
 24. An MR effect sensor as claimed in claim 22 , wherein said MR effect element comprises a laminate film implemented by a unit consisting of an Si layer, a diffusion control layer, a metal lower layer, a free magnetic layer, a nonmagnetic layer, a fixed layer, and a magnetic fixing layer.
 25. An MR effect sensor as claimed in claim 24 , wherein said diffusion control layer comprises one of Ta, Hf, Zr, W, Cr, Ti, Mo, Pt, Ni, Ir, Cu, Ag, Co, Zn, Ru, Rh, Re, Au, Os, Pd, Nb and V.
 26. An MR effect element as claimed in claim 24 , wherein said diffusion control layer comprises one of an oxide and a nitride of Si, Ta, Al, Ti, V, Cr, Mn, Hf, Zr, W, Mo, Ni and Zn and a mixture of said oxide and said nitride.
 27. An MR effect element as claimed in claim 24 , wherein said diffusion control layer comprises one of a mixture and a laminate of an oxide and a nitride of Si, Ta, Al, Ti, V, Cr, Mn, Hf, Zr, W, Mo, Ni and Zn.
 28. An MR sensing system comprising: an MR effect sensor comprising a lower shield layer, a lower gap layer and an MR effect ele-nmnt laminated on a substrate, said shield layer and said MR effiect element each being patterned, a longitudinal bias layer and a lower electrode layer sequentially laminated in such a manner as to contact edges of said MR effect element, and an upper gap layer and an upper shield layer sequentially laminated on said longitudinal bias layer and said lower electrode layer; means for producing a current to flow through said MR effect sensor; and means for sensing a change in an MR ratio of said MR effect sensor as a function of a magnetic field sensed.
 29. An MR sensing system comprising: an MR effect sensor comprising a lower gap layer and an MR effect element laminated on a substrate, said shield layer and said MR effect eltment each being patterned, a longitudinal bias layer and a lower electrode layer sequentially laminated in such a manner as to partly overlap said MR effect element, and an upper gap layer and an upper shield layer sequentially laminated on said longitudinal bias layer and said lower electrode layer; means for producing a current to flow through said MR effect sensor; and means for sensing a change in an MR ratio of card MR effect sensor as a function of a magnetic field sensed.
 30. A magnetic storage system comprising: a magnetic recording medium having a plurality of tracks for recording data; a magnetic recording system for writing data in said magnetic recording medium; an MR sensing system comprising an MR effect sensor, means for producing a current to flow through said MR effect sensor, and means for sensing a change in an MR ratio of said MR effect sensor as a function of an magnetic field sensed, said MR effect sensor comprising a lower shield layer, a lower gap layer and an MR effect element laminated on a substrate, said shield layer and said MR effect eIement each being patterned, a longitudinal bias layer and a lower electrode layer sequentially laminated in such a manner as to contact edges of said MR effect element, and an upper gap layer and an upper shield layer sequentially laminated on said longitudinal bias layer and said lower electrode layer; and means connected to said magnetic recording system and said MR sensing system for effecting a movement to any one of the tracks of said magnetic recording medium selected.
 31. A magnetic storage system comprising: a magnetic recording medium having a plurality of tracks for recording data; a magnetic recording system for writing data in said magnetic recording medium: an MR sensing system comprising an MR effect sensor, means for producing a current to flow through said MR effect sensor, and means for sensing a change in an MR ratio of said MR effect sensor as a function of an magnetic field sensed, seid MR effect sensor comprising a lower shield layer, a lower gap layer and an MR effect element laminated on a substrate, said shield layer and said MR effect element each being patterned, a longitudinal bias layer and a lower electrode layer sequentially laminated in such a manner as to partly overlap said MR effect element, and an upper gap layer and an upper shield layer sequentially laminated on said longitudinal bias layer and said lower electrode layer; and means connected to said magnetic recarding system and said MR sensing system for effecting a movement to any one of the tracks of said magnetic recording medium selected. 